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Elastic interactions between colloidal microspheres and elongated convex and concave nanoprisms in nematic liquid crystals

机译:胶体微球与细长凸起之间的弹性相互作用   向列液晶中的凹和纳米棱柱

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摘要

We study mutual alignment and interactions between colloidal particles ofdissimilar shapes and dimensions when dispersed in a nematic host fluid. Convexpentagonal and concave starfruit-shaped nanoprisms and microspheres inducedipolar or quadrupolar director structures. The ensuing elastic pairinteractions between microspheres and nanoprisms are highly dependent on thenanoparticle shape being omnidirectionally attractive for convex prisms butstrongly anisotropic for concave prisms. Elastic deformations due to sphericalparticles cause well-defined alignment of complex-shaped nanoparticles atdistances much larger than the microsphere size. We characterize distance andangular dependencies of elastic pair interaction forces, torques, and bindingenergies. The studied elasticity-mediated self-assembly of metal and dielectricnanoparticles with dissimilar shapes and sizes opens new possibilities forself-assembly based fabrication of structured mesoscopic composites withpredesigned properties.
机译:我们研究分散在向列型主流体中时,形状和尺寸不同的胶体颗粒之间的相互排列和相互作用。凸五角形和凹形杨桃形纳米棱镜和微球诱导的双极或四极指向矢结构。随之而来的微球和纳米棱镜之间的弹性对相互作用很大程度上取决于纳米粒子的形状,而纳米粒子的形状对于凸棱镜是全方位吸引的,而对于凹棱镜则是各向异性的。球形颗粒引起的弹性变形导致复杂形状的纳米颗粒的明确排列,其排列远大于微球尺寸。我们表征了弹性对相互作用力,扭矩和结合能的距离和角度依赖性。对具有不同形状和大小的金属和介电纳米粒子进行弹性介导的自组装研究,为基于自组装的结构化介观复合材料的预设计制造提供了新的可能性。

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